Magnesium Turnings Activation

Magnesium Turnings Activation

DESCRIPTION:
Activation of the magnesium surface is often necessary for successful Grignard reactions. A common practice is the use of small quantities of iodine or 1,2-dibromoethane as activating additives, which induce initiation of the reaction. Diisobutylaluminum hydride has been used to activate magnesium turnings for the manufacture of alkylmagnesium halides. Sonication has been found to be a very effective method of activation. Primary and secondary alkyl chlorides can be converted into alkylmagnesium chloride in toluene containing small quantities of diethyl ether or THF with ultrasound assistance.
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Description
Technical Parameters
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  • Effective activation can also be achieved by stirring magnesium particles without solvent under an inert atmosphere. Photomicrographic observation of magnesium surfaces during Grignard reactions with and without activation has shown that the reaction proceeds at discrete initiation sites on the magnesium surfaces. Addition of iodine increases the density of reactive sites on the magnesium surfaces, while sonication does not appear to affect the magnesium surfaces directly. Highly reactive forms of magnesium can be used to achieve Grignard reaction of substrates, which are inert under the conditions described above, or which tend to give rise to side reactions, in particular Wurtz coupling.

  • A slurry of finely powdered magnesium can be obtained by condensation of magnesium vapor into diethyl ether or THF. Highly reactive magnesium, known as Rieke magnesium, can be obtained by reduction of magnesium chloride with potassium in THF. Rieke magnesium is sufficiently reactive to induce Grignard reaction of alkyl fluorides, and for the preparation of unstable alkylmagnesium halides at low temperatures.

 

 

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Magnesium Chips
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Magnesium Chips
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Magnesium Chips

 

 

 

Guide & Advantage
 

Magnesium reacts with anthracene in THF to form Mg(anthracene) (THF)3 complex 2.

Complex 2 decomposes in solvents other than THF to give an activated form of magnesium, which can be used to metallate allylic, benzylic, and propargylic halides. Polymer- and silica-supported derivatives of complex 2 have been reported to effect benzylic metallation in THF.

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Package & Delivery
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Use bags, metal pail, or paper pail to pack, the underlayer are plastic bag.

 

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Transport Tool: Trucks or containers.

 

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Storage Methods: The storehouse should be ventilated, dry, fire preventing, wet preventing, static preventing and the hermetic goods.

 

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Our Services

Factory direct supply

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Particle size and Package Can customized

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Strickly quality control system and advanced testing equipments

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Good aftersale service.

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Our Locations

As a technical-commercial oriented company, NY2 has grown to have now five offices located in China Mainland, lndia, Turkey, Hong Kong, German with either sales or warehouse function.

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Magnesium Powder

 

Product Grade Shape Composition(%) AD(g/cm3) Particle Size
Magnesium
Powder
SMP358 Nearly Spherical >Mg 99% 0.86-0.92 35-80 mesh
SMP451 Nearly Spherical >Mg 99% 0.86-0.92 45-100 mesh
MP30 lrregular >Mg 99% 0.64-0.73 30-80 mesh
MP60 lrregular >Mg 99% 0.64-0.73 60-200 mesh
MP150 lrregular >Mg 99% 0.76-0.85 -150 mesh
Can be produced according to customer specifications

 

Magnesium Granules

 

Product Grade Shape Composition(%) AD(g/cm3) Particle Size
Magnesium
Granules
MG12 Particles or spheres ≥99.5% - 12-35 mesh
MG20 Particles or spheres ≥99.5% - 20-80 mesh
MG100 Particles or spheres ≥99.5% - 100mesh all pass
Can be produced according to customer specifications

 

Magnesium Turning Chips

 

Product Grade Shape Composition(%) AD(g/cm3) Particle Size
Magnesium
Turning Chips
MS6 Chips ≥99.7% - 6mesh All pass
MS840 Chips ≥99.7% - 8-40mesh
MS2080 Chips ≥99.7% - 20-80 mesh
Can be produced according to customer specifications

 

Magnesium Alloy Chips

 

Product Grade Shape Composition(%) AD(g/cm3) Particle Size
Magnesium
Alloy Chips
AZ91D lrregular Mg90.43; AI8.9; Zn0.43 - 30-80 mesh
ZK61 lrregular Mg94.46; AI0.0006
Zn5.19
- 30-80 mesh
Can be produced according to customer specifications

 

Magnalium Powder

 

Product Grade Shape Composition(%) AD(g/cm3) Particle Size
Magnalium
Powder
AMAP50 lrregular AI:50±2%; Mg:50±2% 0.76-0.85 60-200 mesh
Can be produced according to customer specifications

 

Magnesiun Desulphurization Reagent

 

Product Grade Shape Composition(%) AD(g/cm3) Particle Size
Magnesiun Desulphurization Reagent PSMp1080 lrregular ≥Mg 92% 0.75-0.95 2-0.18mm
(10mesh~80mesh)
Can be produced according to customer specifications

 

 

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